Other Journal Details
Mandatory Fields
Rhen, FMF and Coey, JMD
2006
March
JOURNAL OF PHYSICAL CHEMISTRY B
Magnetic field effect on autocatalysis: Ag and Cu in concentrated nitric acid
Published
Optional Fields
110
12
6274
6278
The partial suppression of corrosion of Ag and Cu in concentrated nitric acid solution by a magnetic field of up to 5 T was studied. The corrosion current density of these metals was found to diminish with magnetic field and rotation speed in a rotating disk electrode experiment. The suppression of corrosion is associated with removal of the catalyst HNO2 from the electrode and passivation of the electrode surface. The Lorentz force was identified as the driving force responsible for the partial suppression of corrosion. A model based on the partial areas associated with active and passive regions on Ag and Cu electrodes is introduced to explain the dependence of the current density on the applied magnetic field.
10.1021/jp057585+
Grant Details